Permeability & Tortuosity Measurement by Mercury Porosimetry.

 


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Sample permeability and tortuosity testing is offered as an extension to our standard Mercury Intrusion Porosimetry analysis which includes calculation of bulk density and sample porosity.

Permeability is determined using a Micromeritics AutoPore instrument through the application of a large number of data points covering regions of significant intrusion. The analysis report includes details of sample density and porosity and therefore gives a direct measurement of both porosity and permeability from the same analysis. This has proven to be particularly applicable and beneficial to the hydrology, petrology, geotechnical testing and catalysis where the technique provides huge time saving when compared to alternative permeability testing methods. 

Permeability (in mD) is calculated using the threshold pressure of mercury intrusion, the sample envelope and true density values. Envelope density is determined from the mercury intrusion data and true density can be entered either as a known or assumed value for the material or measured using our helium pycnometry option. This may be undertaken on a representative sample from a batch or may be determined prior to the permeability / porosity analysis itself. Such an option is useful where issues of sample homogeneity exist. Our density analysis page provides more details on these techniques additional options for determining porosity within given ranges.

geotechnical permeability testing with porosity using mercury intrusion porosimetry

Mercury Porosimetry Intrusion Curve for permeability and porosity testing

Sample tortuosity provides a measure of the difference between the actual path length through sample pores and the geometrically shortest distance through the sample. The generation of tortuosity data requires the generation of permeability data and a known value of the BET surface area of the sample. The surface area may be provided from a known value or can be measured using our BET surface area analysis option.

The information provided by the permeability porosity and tortuosity analysis options as well as our standard mercury porosimetry tests is detailed below.

Mercury Porosimetry Analysis

Density Option

Permeability Analysis

Tortuosity Analysis

Total Intrusion Volume

Bulk Density

Permeability (mD)

Tortuosity

Total Pore Area

Skeletal Density

Threshold Pressure

Tortuosity Factor

Average Pore Diameter

Porosity (volume %)

Characteristic Length

 

Median Pore Diameter (by area)

  Total Pore Volume1

  Threshold pore size2

 

Median Pore Diameter (by vol)

 

   Total Pore Volume1

 

1. Total Pore Volume may be calculated if bulk density and true density of the sample are known and is reported separately from the generated mercury porosimetry reports.

2. The Threshold Pore Size (diameter) is calculated from the mercury intrusion curve and is reported separately from the generated permeability reports.